Open systems with gain and loss, described by non-trace-preserving, non-Hermitian Hamiltonians, have been a subject of intense research recently. The effect of exceptional-point degeneracies on the dynamics of classical systems has been observed through remarkable phenomena such as the parity-time (PT) symmetry breaking transition, asymmetric mode switching, and optimal energy transfer. On the other hand, consequences of an exceptional point for quantum evolution and decoherence are hitherto unexplored. I will describe how we use post-selection on a three-level superconducting transmon circuit with tunable Rabi drive, dissipation, and detuning to carry out quantum state tomography of a single dissipative qubit in the vicinity of its exceptional point. Quantum state tomography reveals the PT symmetry breaking transition at zero detuning, decoherence enhancement at finite detuning, and a quantum signature of the exceptional point in the qubit relaxation state. Our observations demonstrate rich phenomena associated with non-Hermitian physics such as non-orthogonality of eigenstates in a fully quantum regime and open routes to explore and harness exceptional point degeneracies for enhanced sensing and quantum information processing.